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  • Ab-initio calculations for the adsorption of H2O on a carbene-like zigzag site at the edge of a poly aromatic hydrocarbon. Videos with the frontal and lateral views of the intrinsic reaction coordinate calculation are provided to emphasize the rotational process. This information is a relevant evidence of the electronic effects that induce rotation of the water molecule and provides explanation from ab initio procedures to the slow H2O adsorption sometimes attributed to diffusion problems.
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  • this Data reveals all results founded in this research paper
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  • Palynomorph assemblages and palynofacies analysis have been performed on several core samples from the Devonian–Carboniferous deposits identified in five wells located in the eastern part of the Moesian Platform. The investigated sections include, in ascending stratigraphic order, the Ţăndărei, Smirna, Călăraşi and Vlaşin formations. Based on stratigraphic distribution of key taxa identified (miospores, chitinozoans, acritarchs), seven biozone intervals (four for Devonian and three for Carboniferous) have been recognized. The oldest samples were dated as being part of the micrornatus-newportense (MN) – lower part of breconensis-zavallatus (BZ) interval zones (early Devonian), while the younger ones are assigned to the kosankei-varioreticulatus (KV) – nobilis-junior (NJ) interval zones (late Carboniferous). Palynofacies observations suggest a more distal depositional environment during the period between Lochkovian and Pragian times, followed by some proximal/fluvio-deltaic conditions in Emsian–early Eifelian (the top of Ţăndărei Formation). The upper Tournaisian to Serpukhovian sedimentary rocks of the Călăraşi and lower part of Vlaşin formations were deposited in inner neritic environments. Mud-dominated dysoxic/anoxic conditions prevailed in the Bashkirian, which were quickly succeeded by a deltaic deposition and oxidizing environments which persisted up to Moscovian. The lower Devonian terrestrial palynoflora is dominated by trilete spores which belong to the lowland vegetation of a non-forest mire palaeoecological group. The Carboniferous deposits yielded only terrestrial palynomorphs of various types of arborescent and herbaceous lycopsids and ferns, suggesting different habitats such as non-flooded wetlands or swamps within coastal plain and continental interiors. These assemblages of Carboniferous miospores are an indication of the neutral-humid climatic conditions which existed at the time of deposition.
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  • There is a detailed Readme.pdf in the files for the informations about the dataset. The main purpose is providing a dataset for the vibration behavior of a robot manipulator system under the control input of model-associative vibration control (MAVC) prodecure. Velocity profile is shown as [∗,𝑡𝑐𝑜𝑛,𝑡𝑑𝑒𝑐,𝑡𝑚] in study. In the case studies for both simulations and experiments, the parameters are varied as follows; 𝑡𝑐𝑜𝑛 can be valued as 0, 𝑡1ℎ or 2𝑡1ℎ, 𝑡𝑑𝑒𝑐 can be valued as 𝑡1ℎ,2𝑡1ℎ,3𝑡1ℎ,4𝑡1ℎ or 5𝑡1ℎ and 𝑡𝑚 can be valued as 1 or 1.5 seconds for corresponded 90 or 135 angular displacements. Thus thirty different velocity profiles are produced with aim to performed on system. Cases are invastigated with and without performing the MAVC procedure. Than the robot manipulator is examined for both unloaded and loaded cases, therefore total one hundred twenty cases are occured. More details can be found in related study.
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  • Western blots and soft agar images
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  • Supplementary Data. Includes Excel data tables for ages and shapefiles for ages, geomorphology and ice-sheet reconstruction.
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  • Non-marginal (average) AWARE CFs and WSI CFs: We provide a shapefile, CSV file and KML file of the average AWARE characterization factors (CFs) based on the marginal AWARE CFs from Boulay et al. (2018). We also provide it together with average WSI factors from Pfister and Bayer (2014), since based on the UNEP SETAC recommendation, AWARE should be used together with an alternative scarcity method to test sensitivities (Jolliet et al. 2018). The XLS version of the average AWARE CFs is available from the original publication: Pfister S, Scherer L, Buxmann K (2020) Water scarcity footprint of hydropower based on a seasonal approach - Global assessment with sensitivities of model assumptions tested on specific cases. Science of The Total Environment. https://doi.org/10.1016/j.scitotenv.2020.138188 DATA structure: The CSV files lists CFs for each month (01 to 12) and each methods: AWARE_01 stands for original marginal AWARE CFs of January, AWARE_a_01 represents the newly calculated average AWARE CFs for January, WSI_01 are the marginal WSI CFs for January and WSI_AVG_01 the average WSI CFs for January. The CSV file can be linked to WaterGAP watersheds based on the "BAS34S_ID" . The WaterGAP shapefile is e.g. available at http://www.wulca-waterlca.org/aware.html. The Shapefile and KML file follows the same order but are already linked to the watershed shapefile.
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  • The image is an enhanced image sample of ancient ceramics. M_ming means plum vase in the Ming dynasty. M_qing means plum vase in the Qing dynasty. Y_ming means Jade pots of spring vase in the Ming dynasty. Y_qing means Jade pots of spring vase in the Qing dynasty.
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  • The THA-col composite was prepared by mixing THA (2.5% w/v) and col 1 (0.5% w/v) with simultaneous gelation induced by hydrogen peroxide and horseradish peroxidase for THA and neutralization for col. The composite biomaterial ink was characterized for fibrillation by turbidity measurement, fluorescence microscopy and rheological properties (shear thinning behaviour and amplitude sweep) were assessed. Anisotropic properties were introduced upon 3D bioprinting (3D DiscoveryTM, RegenHU) the biomaterial ink. Cellular behaviour was investigated by embedding human mesenchymal stromal cell (MSC) spheroids into the hydrogel. Cell migration as well as chondrogenic differentiations was analysed over time by microscopy with subsequent image analysis (Oval plugin, ImageJ, NIH), gene expression analysis, histological stainings and glycosaminoglycan and DNA quantification. The fibrillation of col 1 and the homogenous distribution of the fibers within THA was shown by second harmonic generation imaging and fluorescent imaging and confirmed by turbidity measurement. After 3D bioprinting an anisotropic alignment of col fibrils was achieved that guided cell migration along the fiber orientation. Cell migration of hMSC spheroids showed similar behavior comparing THA-col and col whereas no migration was present for THA only. Chondrogenic differentiation resulted in an increase in cartilage related genes (col 2, aggrecan) with low tendency of hypertrophy (col X, col I, RunX2). Cartilage like matrix deposition was further corroborated by quantification of GAGs within samples that showed an overall increase within 21 days of culture similar to hMSC pellet control group. Safranin O staining resulted confirmed production of proteoglycans . Extrusion based printing has been investigated to produce scaffolds with anisotropic properties on microscale exploiting the shear forces inducing alignment of col fibres within a shear thinning HA matrix. The combination of the two matrix components brings unique features and advantages addressing cell migration, differentiation and material tissue integration compared to the single polymers. THA-col biomaterial has shown its potential for cartilage tissue engineering and represents a potential injectable material for cell free cartilage treatment.
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