Data for the synthesis and characterization of fluorene-containing β-diketonato ligands and their Rhodium(I) complexes
Three novel β-diketonato ligands were synthesized containing the fluorene-group as substituent. Rhodium(I) complexes thereof were synthesized as reported in Fluorene-containing β-diketonato ligands and their Rhodium(I) complexes. The 1H and 13C NMR’s of all 6 compounds are reported. Spectroscopic data of concentration variations vs absorbance intensities are given for ligands and rhodium(I) complexes showing that they follow the Beer-Lambert law and extinction coefficients (ԑ) are determined. Fluorescence quantum yields are determined and graphs showing the integrated fluorescent intensities vs absorbance are shown. The electrochemistry data of compounds 1 – 6 are reported for scan at 100 - 500 mV/s scan speeds.
Steps to reproduce
NMR - Bruker 600 MHz AVANCE II NMR spectrometer with Topspin 3.6.2 software. UV/vis - Cary 60 spectrophotomer. Fluorescence - Cary Eclipse spectrophotometer. Spectra were integrated using OriginPro 2019b software version 126.96.36.199. Electrochemistry - BAS 100 B/W potentiostat