Data for the synthesis and characterization of fluorene-containing β-diketonato ligands and their Rhodium(I) complexes

Published: 22-02-2021| Version 1 | DOI: 10.17632/2vcvjycf63.1
Contributor:
Eleanor Fourie

Description

Three novel β-diketonato ligands were synthesized containing the fluorene-group as substituent. Rhodium(I) complexes thereof were synthesized as reported in Fluorene-containing β-diketonato ligands and their Rhodium(I) complexes. The 1H and 13C NMR’s of all 6 compounds are reported. Spectroscopic data of concentration variations vs absorbance intensities are given for ligands and rhodium(I) complexes showing that they follow the Beer-Lambert law and extinction coefficients (ԑ) are determined. Fluorescence quantum yields are determined and graphs showing the integrated fluorescent intensities vs absorbance are shown. The electrochemistry data of compounds 1 – 6 are reported for scan at 100 - 500 mV/s scan speeds.

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Steps to reproduce

NMR - Bruker 600 MHz AVANCE II NMR spectrometer with Topspin 3.6.2 software. UV/vis - Cary 60 spectrophotomer. Fluorescence - Cary Eclipse spectrophotometer. Spectra were integrated using OriginPro 2019b software version 9.6.5.169. Electrochemistry - BAS 100 B/W potentiostat