Pressure Decay Data for Measuring CO2-Water Diffusion Coefficient

Description

Carbon dioxide (CO2) storage in deep aquifers is a promising solution to mitigate anthropogenic CO2 emissions. CO2 solubility in brine results in a non-buoyant phase providing an effective trapping mechanism. However, field observations have shown that this diffusion-driven mechanism is a relatively slow process. Accurate determination of CO2 diffusion coefficient is, therefore, essential. The pressure decay method is a widely employed technique for measuring diffusion coefficients of gases in bulk liquids or porous media. It involves introducing a volume of gas on top of the liquid in a closed system and monitoring the pressure decay over time. While the method is generally simple and accurate, artifacts from natural convection can significantly influence the measured diffusion for liquids that exhibit an increase in density due to gas dissolution. This work presents an improved experimental approach for measuring CO2 diffusion coefficients in water in a convection-fee system. Our setup consisted of single open-ended borosilicate capillary tubes filled with water inside a high-pressure vessel filled with CO2 gas. The water-filled capillary tubes were placed with their open ends facing down. This configuration exhibits bottom-top diffusion leading to gravity-stable CO2 diffusion in water free of gravity-induced convection and viscous fingering. The effects of pressure and salinity variations confirm the agreement between our results and values reported in the literature. We also performed experiments and numerical modeling to determine the effective diffusion coefficient of CO2 in a porous medium. The proposed technique can be used to measure the diffusion coefficients for other gas-liquid systems. This data set (data.zip) includes the measured data and the modeling code used in this study, which are: 1- ExperimentalData.xlsx : measurred pressure decay data to calculate CO2 solubility in water 2- approximateSolution.mlx : analytical solution to fit the experimetnal data using 1 term in the infinite series 3- BaseCase-0M.xlsx : measurred pressure decay data to calculate CO2 solubility in water in porous media, used in approximateSolution.mlx 4- generalSolution.m : analytical solution to fit the experimetnal data using 1, 2 and 20 terms in the infinite series 5- tp_data.mat : time-prssure data set used with generalSolution.m

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