Schmidt number data pertaining to autothermal methanol steam reforming reactors at different reaction temperatures
Description
To obtain the solution of the Schmidt number problem, numerical simulations are performed using fluid mechanics. Schmidt number is a dimensionless number defined as the ratio of momentum diffusivity and mass diffusivity, and it is used to characterize fluid flows in which there are simultaneous momentum and mass diffusion convection processes. The Schmidt number is the ratio of the shear component for diffusivity to the diffusivity for mass transfer. The Schmidt number physically relates the relative thickness of the hydrodynamic layer and mass-transfer boundary layer. The heat transfer analog of the Schmidt number is the Prandtl number. The ratio of thermal diffusivity to mass diffusivity is the Lewis number. The reactor system comprises two separate sets of flow channels, which are located between spaced, highly heat-conductive metal or ceramic separating walls. The medially located separating walls have different catalysts on opposed surfaces. These catalysts are selected for the particular reaction taking place in the adjacent reaction zone. The reactor provides for continuous and simultaneous reaction of two different process reaction streams in the channels defined between the walls, wherein a first process reaction stream undergoes a high temperature exothermic reaction in the first set of flow channels and a second process reaction stream undergoes an endothermic heat-consuming reaction in the second set of flow channels separated from the first set of flow channels by the heat transfer separating walls. More specifically, the reactor system includes a set of reforming channels for steam reformation of methanol and a set of oxidation channels for heating the reactor system to operating temperature. A separating wall therefore separates two adjacent reaction zones and also functions to transfer heat from the oxidation occurring at the catalyst surface in the oxidation zone directly to the reforming catalyst coated on the opposed surface. The reactor system is operated using excess air and water steam. Methanol and air are mixed homogeneously and the mixture is fed directly into the oxidation channels in a specific ratio. Contributor: Junjie Chen, E-mail address: koncjj@gmail.com, ORCID: 0000-0002-5022-6863, Department of Energy and Power Engineering, School of Mechanical and Power Engineering, Henan Polytechnic University, 2000 Century Avenue, Jiaozuo, Henan, 454000, P.R. China
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To facilitate computational modeling of transport phenomena and chemical kinetics in the flowing system of complex chemical reactions involving gas-phase and surface species, steady-state analyses are performed and computational fluid dynamics is used. ANSYS FLUENT handles thermodynamic properties, transport properties, gas-phase equation-of-state, and chemical kinetics. The boundary conditions relate macroscopic fluid flow at a catalytically active surface to the rates of surface reactions. The endothermic process is modeled in such a way as to take into account methanol steam reforming and decomposition and the water-gas shift reaction.