Data for: Time-resolved photoacoustic calorimetry of organometallic ligand substitution in alkane solvents: molybdenum-alkane sigma complex controls ultrafast ligand addition to molybdenum pentacarbonyl

Published: 3 Mar 2018 | Version 1 | DOI: 10.17632/ghhzw8ssv6.1
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Description of this data

Tables and plots photoacoustic calorimetry signal amplitudes and lifetimes, observed rate constants as a function of ligand concentrations for substitution with molybdenum hexacarbonyl in alkane solvents. Solvent include pentane, hexane, heptane, octane, decane and dodecane. Plots of PAC amplitudes as a function of solvent expansivity to determine reaction enthalpies and reaction volumes. Ligands include acetonitrile, triethylphosphine oxide, triethylphosphine, tetrahydrofuran, tetrahydrothiophene, pyridine, triethylphoshite, triethylphosphate, and 1-bromobutane.

Experiment data files

peer reviewed

This data is associated with the following peer reviewed publication:

Time-resolved photoacoustic calorimetry of organometallic ligand substitution in alkane solvents: Molybdenum-alkane σ bond controls fast ligand addition to molybdenum pentacarbonyl

Published in: Chemical Physics

Latest version

  • Version 1

    2018-03-03

    Published: 2018-03-03

    DOI: 10.17632/ghhzw8ssv6.1

    Cite this dataset

    Burkey, Ted; Gittermann, Shannon (2018), “Data for: Time-resolved photoacoustic calorimetry of organometallic ligand substitution in alkane solvents: molybdenum-alkane sigma complex controls ultrafast ligand addition to molybdenum pentacarbonyl ”, Mendeley Data, v1 http://dx.doi.org/10.17632/ghhzw8ssv6.1

Categories

Physical Chemistry, Photochemistry, Transition Metals Coordination Chemistry

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