Data on synthesis and characterization of sulfonated poly(phenylnorbornene) and polymer electrolyte membranes based on it

Published: 20 August 2019| Version 1 | DOI: 10.17632/wcx58k2rp2.1
Contributors:
Oleg Morozov,
Boris Bulgakov,
Анна Иванченко,
Svetlana Shachneva,
Sergey Nechausov,
Maxim Bermeshev,
Alexey V. Kepman

Description

This dataset obtained from the synthesis and characterization of sulfonated poly (norbornene) and ionic polymer membranes based on it. The polymer was synthesized via one-pot two step ring-opening metathesis polymerization (ROMP) and subsequent reduction by p-toluenesulfonyl hydrazide. The dataset contains raw spectra and thermal data of hydrated poly (phenyl norbornene) (HPPhNB), sulfonated hydrated poly (phenyl norbornene) (SHPPhNB), imidazolium sulfonated hydrated poly (phenyl norbornene) (SHPPhNB-Im) and 1-methylimidazolium sulfonated hydrated (phenyl norbornene) (SHPPhNB-MIm) as 1H NMR free induction decays (FID), raw FTIR spectra and DSC curves. Data from electrochemical impedance spectroscopy (EIS) for membranes prepared from ionomers and blend with PVDF membranes are provided. Images of both surfaces and cross-section of blend membranes obtained by scanning electron microscopy (SEM) are presented.

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Institutions

Moskovskij gosudarstvennyj universitet imeni M V Lomonosova

Categories

Nuclear Magnetic Resonance, Fourier Transform Infrared Spectroscopy, Differential Scanning Calorimetry, Scanning Electron Microscopy, Ionic Conductivity, Impedance

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