Data for: A stereoselective synthesis of (R)-5-hydroxy-3-(4-methoxyphenethyl)cyclohex-2-enone, towards total synthesis of Prelunularin

Published: 26 April 2021| Version 1 | DOI: 10.17632/x9rk5kthyt.1
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KOMMU NAGAIAH

Description

A first chiral strategy for synthesis of (R)-5-hydroxy-3-(4-methoxyphenethyl) cyclohex-2-enone reported. Key transformation includes Barbier allylation, ionic hydrogenation, Jefferey reaction, Katsuki Sharpless asymmetric epoxidation, reductive opening of epoxide and ring closing metathesis

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Synthesis

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