Reaction mechanism: of the work (Kinetic Modeling of NOx Formation and Consumption during Methanol and Ethanol Oxidation)
Description
This work presents a newly developed kinetic mechanism for the oxidation of methanol and ethanol and their fuel interaction with NOx (NO and NO2) chemistry in jet-stirred and flow reactors, freely propagating and burner-stabilized premixed flames, as well as shock tubes. A number of published experiments have been selected to demonstrate that important features of the CH3OH/NOx and C2H5OH/NOx chemistry are well captured by the here derived, broadly validated reaction mechanism. This work is the supplementary material to the work: Kinetic Modeling of NOx Formation and Consumption during Methanol and Ethanol Oxidation. https://doi.org/10.1080/00102202.2019.1606804
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The rate parameters adopted to develop the detailed chemical kinetic mechanism of H2 and CO is mostly based on the recommendations of Baulch et al. 2005 (Journal of Physical and Chemical Reference Data 34, 757 (2005). https://doi.org/10.1063/1.1748524).