Inorganica Chimica Acta

CIF files for complexes discussed in the article and data validation reports (CHECKCIF)

Sqlite3 database contains values of QTAIM delocalization index used for plotting Figure 1 and values of electron density, laplacian of electron density, and few others descriptors at bond critical points for complexes PtCo(OOCMe)4(H2O), PtIn(OOCMe)5, PtCo(SOCMe)4(H2O) and palladium analogs.

Geometry optimization, thermochemical analysis and natural bond orbital analysis of bimetallic HXTA complexes at b3lyp/6-311++g(d,p)

Primary 19F-NMR data for metal competition experiments. See tables S4, S8, and S12 in Supporting Information

Data used for preparation of figures in the manuscript and a particular rate constants calculated from kinetic runs.

The data include: the original single-crystal crystal data: om.ls, om.p4p, om.raw; the original data of IR, TG, UV-Vis, XRD and fluorescence spectroscopy.

The added data contain Cif and CheckCif files.

Excel spreadsheets used for the calculation of half-wave potentials and peak potential differences relative to the ferrocenium/ferrocene couple, as well as Randles-Sevcik plots of peak currents vs. square root of sweep rate.

Four binuclear diketonate complexes of boron difluoride have been prepared. Ob-tained complexes contain the following pairs of ligands connected through a sulfur atom with their central carbon atoms: acetylacetone-acetylacetone, acetylacetone-acetoacetic ester, acetylacetone-dibenzoylmethane, acetylacetone-benzoylacetone. Molecular and crystal structure have been identified for three complexes. Their structure is similar to the one of aromatic sulfides. Effect of γ-substituents on chelate cycle structure and on the substituents next to β-carbon atoms has been discussed.

Spectroscopic data, biological data