Applied Catalysis B: Environmental

F(R), FT-IR and Raman spectra included in the manuscript

Video showing the movement of Bi2S3 quantum dots observed during TEM imaging.

The video shows the movement of Bi2S3 quantum dots on the TiO2 surface during TEM microscopic analysis.

He-TPD-MS and DFT document

The data contains all data and code needed to reproduce the results of the manuscript "A Machine Learning Framework for the Analysis and Prediction of Catalytic Activity from Experimental Data."

Supporting information to the article "Understanding the Reversible and Irreversible Deactivation of Methane Oxidation Catalysts" by Rasmus Lykke Mortensen,[a,b] Hendrik-David Noack[b], Kim Pedersen,[b] Maja A. Dunstan,(a) Fabrice Wilhelm,(c) Andrei Rogalev,(c) Kasper S. Pedersen,(a)Jerrik Mielby*[a] and Susanne Mossin*[a][a] R. L. Mortensen, Prof. S. Mossin, and Dr. J. Mielby, DTU Chemistry, Technical University of Denmark, Kemitorvet 207, DK-2800 Kgs. Lyngby, Denmark, slmo@kemi.dtu.dk[b] H.-D. Noack, Dr. K. Pedersen, Umicore Denmark Aps, Kogle Allé 1, DK-2970 Hørsholm, Denmark[c] Dr. Fabrice Wilhelm, Dr. Andrei Rogalev, ESRF – The European Synchrotron, BP 220, 38043 Grenoble Cedex 9, France.

Supporting information to the article "Understanding the Reversible and Irreversible Deactivation of Methane Oxidation Catalysts" by Rasmus Lykke Mortensen,[a,b] Hendrik-David Noack[b], Kim Pedersen,[b] Maja A. Dunstan,(a) Fabrice Wilhelm,(c) Andrei Rogalev,(c) Kasper S. Pedersen,(a)Jerrik Mielby*[a] and Susanne Mossin*[a][a] R. L. Mortensen, Prof. S. Mossin, and Dr. J. Mielby, DTU Chemistry, Technical University of Denmark, Kemitorvet 207, DK-2800 Kgs. Lyngby, Denmark, slmo@kemi.dtu.dk[b] H.-D. Noack, Dr. K. Pedersen, Umicore Denmark Aps, Kogle Allé 1, DK-2970 Hørsholm, Denmark[c] Dr. Fabrice Wilhelm, Dr. Andrei Rogalev, ESRF – The European Synchrotron, BP 220, 38043 Grenoble Cedex 9, France.

Supplementary files for article A light-management film layer induces dramatically enhanced acetate production in photo-assisted microbial electrosynthesis systems. A light-management system consisting of a Al-doped ZnO (AZO) film layer was combined for the first time with different bio-photocathodes (Serratia marcescens Q1 electrotroph immobilized on g-C3N4, MnFe2O4 or MnFe2O4/g-C3N4) to significantly enhance acetate production from bicarbonate in photo-assisted microbial electrosynthesis systems (MES). The AZO light-management system exhibiting optical properties independent of the light incident angle mitigated the shielding effect of light by electrotrophs, increasing light trapping and decreasing light reflection, ultimately allowing higher rates of photon absorption and redistributions of photons over the photo-active layers. As a result, more reducing equivalents as H2 produced up to 242% (g-C3N4/AZO-filter) and 543% (g-C3N4/AZO) increase in acetate production at coulombic efficiencies of 70% (g-C3N4/AZO-filter) and 81% (g-C3N4/AZO). The record high solar-to-acetate efficiency obtained with the MnFe2O4/g-C3N4/AZO biocathode was 3.20%. The light-management system proposed in this study opens a new promising way to construct efficient bio-photocathodes for inorganic carbon reduction in photo-assisted MES.

Supplementary files for article A light-management film layer induces dramatically enhanced acetate production in photo-assisted microbial electrosynthesis systems. A light-management system consisting of a Al-doped ZnO (AZO) film layer was combined for the first time with different bio-photocathodes (Serratia marcescens Q1 electrotroph immobilized on g-C3N4, MnFe2O4 or MnFe2O4/g-C3N4) to significantly enhance acetate production from bicarbonate in photo-assisted microbial electrosynthesis systems (MES). The AZO light-management system exhibiting optical properties independent of the light incident angle mitigated the shielding effect of light by electrotrophs, increasing light trapping and decreasing light reflection, ultimately allowing higher rates of photon absorption and redistributions of photons over the photo-active layers. As a result, more reducing equivalents as H2 produced up to 242% (g-C3N4/AZO-filter) and 543% (g-C3N4/AZO) increase in acetate production at coulombic efficiencies of 70% (g-C3N4/AZO-filter) and 81% (g-C3N4/AZO). The record high solar-to-acetate efficiency obtained with the MnFe2O4/g-C3N4/AZO biocathode was 3.20%. The light-management system proposed in this study opens a new promising way to construct efficient bio-photocathodes for inorganic carbon reduction in photo-assisted MES.

Kinetics, reaction pathways, and mechanism investigation for improved environmental remediation by 0D/3D CdTe/Bi2WO6 Z-scheme catalyst