Data for: SYNTHESIS AND STRUCTURE OF BORON DIFLUORIDE BINUCLEAR  β-DIKETONATES

Name: Data for: SYNTHESIS AND STRUCTURE OF BORON DIFLUORIDE BINUCLEAR β-DIKETONATES
Creator: Irina Svistunova
Published: 2019-11-10T11:10:06.605Z
Keywords: Chemistry

Svistunova, Irina; Puzyrkov, Zahar; Tretyakova, Galina; Sharutin, Vladimir

doi:10.17632/ms38bhwbtn.1

Data for: SYNTHESIS AND STRUCTURE OF BORON DIFLUORIDE BINUCLEAR β-DIKETONATES

Published: 10 November 2019| Version 1 | DOI: 10.17632/ms38bhwbtn.1

Contributors:

Irina Svistunova, Zahar Puzyrkov, Galina Tretyakova, Vladimir Sharutin

Description

Four binuclear diketonate complexes of boron difluoride have been prepared. Ob-tained complexes contain the following pairs of ligands connected through a sulfur atom with their central carbon atoms: acetylacetone-acetylacetone, acetylacetone-acetoacetic ester, acetylacetone-dibenzoylmethane, acetylacetone-benzoylacetone. Molecular and crystal structure have been identified for three complexes. Their structure is similar to the one of aromatic sulfides. Effect of γ-substituents on chelate cycle structure and on the substituents next to β-carbon atoms has been discussed.

Data for: SYNTHESIS AND STRUCTURE OF BORON DIFLUORIDE BINUCLEAR β-DIKETONATES

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