ElectroEnergy - QTNANO - Electrochemical Nitrate and Nitrite Reduction Reaction to Ammonia: Catalytic Aging and Stability of Co3O4 Hexagonal Nanoplates - ACS Appl. Mater. Interfaces, 2026

Published: 29 May 2026| Version 1 | DOI: 10.17632/p2t59rbn4z.1
Contributors:
Matheus Sales, Maykon Souza, Marionir Neto, Samuel Silva, João da Silva, Rafael Yoshimura, João Mauricio, Manuel Winkler, Kauan Gomes, João Souza Jr., Santiago Figueroa, Fabio Lima, Claudio Tormena, Juarez L. F. Da Silva, Italo Mazali, Raphael Nagao

Description

This dataset presents the primary computational inputs and outputs from the published work Electrochemical Nitrate and Nitrite Reduction Reaction to Ammonia: Catalytic Aging and Stability of Co3O4 Hexagonal Nanoplates (DOI: 10.1021/acsami.6c03616). The data are organized into the following categories: 1) CO3O4_clean_slab: Contains analyses of the pristine Co3O4 surfaces, including geometry optimizations, electronic properties, and surface energetics. 2) Co3O4_adsorbed_molecules: Provides calculations for the adsorbed intermediates involved in the nitrate (NO3RR) reduction reactions to ammonia. This section includes geometry optimizations and thermodynamic profiling of the reaction pathways. 3) Co3O4_bulk: Includes calculations for the crystalline bulk phase of Co3O4, featuring structural optimizations and reference energy evaluations. 4) Isolated_molecules: Contains gas-phase calculations for the isolated atoms and molecular reference species (e.g., NO3, NH3, H2O, H2, HNO3, etc.) necessary for thermodynamic corrections and zero-point energy (ZPE) calculations.

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